Most of the time I opt for the DVD Release because I can back it up easier (don't have a Bluray driver and unsure if my current programs work with Bluray) however in some cases I do get the Bluray release, this normally happens because it either comes with something extra (Blood C came with a calendar) or are limited editions (like most of the NISA ones, Puella Magi Madoka Magica)
In some of my NISA Limited Edition Anime and Puella Magi Madoka Magica Limited Edition they come with both the DVD and Bluray Release, when testing out my Bluray Player to make sure it could play US Bluray (because I had brought it for Fate/Zero) all I noticed was that the animation was much more smoother. (increase in)
Because I have a large backlog of anime I still haven't watched when I finish a series I move onto the next or I don't remember enough of the beginning of the series to notice any changes (in some cases even re-watching the DVDs have new scenes, in Madoka Magica I don't remember seeing a scene where Sayaka hold out her soul gem with a red background behind her in my first view of the series, second view was on TV)
So I am wondering, between a Bluray Release of an anime and it's DVD counterpart, does a bluray have more scenes in it or is it just the quality difference?